Product ID:AUTOMATE RED B
MSDS Date:04/17/2000
FSC:6820
NIIN:00-926-8887
Status Code:A
MSDS Number: CKMYW

ROHM AND HAAS CO

100 INDEPENDENCE MALL WEST
PHILADELPHIA, PA 19106-2399
US

Emergency Phone: (800)424-9300/215-592-3000

Info Phone: 215-592-2521

Cage: 77902

TELECHEM INTERNATIONAL, INC

SUNNYVALE, CA 94089-2115 US

Telephone: 916-941-3688

Cage: 1KH20

C.I. SOLVENT RED 164 OR 2-NAPHTALENOL {(PHENYLAZO)PHENYL}

CAS: 71819-51-7

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE

CAS: 100-41-4

RTECS: DA0700000

OSHA PEL 435 MG/M3;100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NON-HAZARDOUS AND OTHER INGREDIENTS

LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:FLAMMABLE LIQUID AND VAPOR. CAUSES
SEVERE EYE IRRIATATION. CAUSES SEVERE DIGESTIVE TRACT IRRITATION.
INHALATION ANY CAUSE DIZZINESS, HEADACHES AND INCOORDINATION.
INGESTION CAN CAUSE DIZZINESS, FAINTN ESS, HEADACHE AND
INCOORDINATION. INGESTION MAY CAUSE INFLAMMATION OF THE LUNGS. MAY
CAUSE MIODERATE SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT
IRRITATION. INGESTION. MAY CASUE NAUSEA, VOMITING, PAI N, UPSET
STOMACH, DIARRHEA. INHALATION MAY CAUSE NAUSEA, VOMITING, UPSET
STOMACH. PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE
IRRITATION.
Explanation of Carcinogenicity:ETHYL BENZENE IS LISTED BY IARC AS A 2B
CARCINOGEN & ACGIH AS AN A3. C.I. SOLVENT RED 164 IS NOT LISTED BY
ANY AGENCY AS A CARCINOGEN. XYLENE IS LISTED BY ACGIH AS AN A4
CARCINOGEN.
Effects of Overexposure:EYES: CAUSES SEVERE IRRITATION . CAN CAUSE
BURNING SENSATION, TEARING, AND REDNESS. SKIN: MAY CAUSE MODERATE
IRRITATION. PROLONGED OR REPEATED CONTACT MAY DRY THE SKIN AND LEAD
TO IRRITATION (I.E. DER MATITIS). MAY BE ABSORBED THROUGH THE SKIN.
CAN CAUSE REDNESS, ITCHING, AND BURNING SENSATION. INHALATION:
IRRITATING TO THE EYES, NOSE, AND RESPIRATORY TRACT. CAN CAUSE
DIZZINESS, HEADACHES, AND INCO ORDINATION, NAUSEA, VOMITING, AND
STOMACH UPSET CAN OCCUR. CAN CAUSE WHEEZING, CAUGHING, SHORTNESS OF
BREATH, AND TIGHTNESS IN THE CHEST. CAN CAUSE ANESTHETIC AND/OR
NARCOTIC EFFECTS.
Medical Cond Aggravated by Exposure:LIVER, KIDNEYS, BLOOD AND/OR
BLOOD-FORMING ORGANS. LUNGS AND RESPIRATORY SYSTEM. SKIN,
REPRODUCTIVE SYSTEM AND/OR REPRODUCTIVE EFFECTS.

First Aid:EYE: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. GET PROMPT MEDICAL ATTENTION. SKIN: IMMEDIATELY FLUSH WITH
WATER. REMOVE CONTAMINATED CLOTHING & SHOES. GET MEDICAL ATTENTION
IF IR RITATION PERSISTS. WASH CLOTHING & SHOESBEFORE REUSE.
INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS DEVELOP, SEEK
IMMEDIATE MEDICAL ATTENTION. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. INGESTION: OBTAIN IMMEDIATE MEDICAL ATTENTION. RINSE
MOUTH THOROUGHLY WITH WATER & GIVE A CUPFUL OF WATER TO DRINK, IF
VOMITING OCCURS, REPEAT RINSING & GIVE ANOTHER CUPFUL OF WATER.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point Method:SCC
Flash Point:=28.3C, 83.F
Lower Limits:1
Upper Limits:7
Extinguishing Media:WATER MAY BE INEFFECTIVE. SMALL FIRES: DRY
CHEMICAL, CARBON DIOXIDE, WATER SPRAY, OR FOAM. LARGE FIRES: WATER
SPRAY, FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:FIRE FIGHTERS AND OTHERS WHO MAY BE EXPOSSED
TO THE PRODUCTS OF COMBUSTION SHOULD BE EQUIPPED WITH
NIOSH-APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS
(SCBA) AND FULL PROTECTIVE CLOTHI NG.
Unusual Fire/Explosion Hazard:HIGH TEMPERATURES CAN CAUSE SEALED
CONTAINERS TO RUPTURE DUE TO A BUILD UP OF INTERNAL PRESSURE. COOL
WITH WATER. VAPORS CAN TRAVEL TO A SOURCE OF IGNITION & FLASH BACK.
DURING A FIRE, IRRITATING & HI GHLY TOXIC GASES MAY BE GENERATED
DURING COMBUSTION OR DECOMPOSITION.

Spill Release Procedures:ISOLATE HAZARD AREA. DENY ENTRY. ELIMINATE ALL
SOURCES OF IGNITION. SAFELY STOP DISCHARGE. CONTAIN MATERIAL, AS
NEEDED, WITH A DIKE OR BARRIER. STOP MATERIAL FROM CONTAMINATING
SOIL, FROM ENTERING SE WERS OR BODIES OF WATER. APPROPRIATE SAFETY
MEASURES & PROTECTIVE EQUIPMENT SHOULD BE USED. USE SUPPLIED AIR
RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA AWAY FRON HEAT, IGNITION SOURCES & DIRECT SUNLIGHT.KEEP
CONTAINERS TIGHTLY CLOSED. WARNING: HOT ORGANIC CHEMICAL VAPORS OR
MISTS CAN SUDDENLY & WITHOUT WARNING COMBUST WHEN MIXED WITH AIR.
IGNITION CAN OCCUR AT TYPICAL ELEVATED TEMPERATURE PROCESS
CONDITIONS
Other Precautions:CONTAINERS SHOULD BE SUPPORTED AND GROUNDED BEFORE
OPENING, DISPENSING, MIXING, POURING AND EMPTYING. OPEN WITH
NON-SPARKING TOOLS. IF CONTAINER IS WARM OPEN BUNG SLOWLY TO
RELEASE INTERNAL PRESSURE.

Respiratory Protection:AVOID BREATHING VAPOR AND/OR MISTS. WEAR
NIOSH/MSHA-APPROVED EQUIPMENT. DETERMINE THE APPROPRIATE TYPE BY
CONSULTING THE RESPIRATOR MANUFACTURER. HIGH AIRBORNE
CONCENTRATIONS MAY NECESSITATE THE USE OF SELF-CONTAINED BREATHNG
APPARATUS (SCBA) OR A SUPPLIED AIR RESPIRATOR. RESPIRATORY
PROTECTION PROGRAMS MUST BE IN COMPLIANCE WITH 29 CFR 1910.134.
Ventilation:LOCAL EXHAST VENTILATION IS RECOMMENDED WHEN VAPORS, MISTS,
OR DUSTS CAN BE RELEASED IN EXCESS OF ESTABLISHED AIRBORNE EXPOSURE
LIMITS(TLVS OR PELS).
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:WEAR CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:AN EYE WASH FACILITY SHOULD BE READILY
AVAILABLE. WEAR PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING, ESPECIALLY
BEFORE EATING, DRINKING, SMOKING AND USING RESTROOM FACILITIES.
PROFESSIONALLY LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
WASH CONTAMINATED GOGGLES, FACESHIELD AND GLOVES. *SPECIAL HANDLING:
THIS PRODUCT MAY CONTAIN TRACE QUANTITIES OF AROMATIC AMINES,
ORTHO-TOLUIDINE AND ANILINE, AT LEVELS LESS THAN 0.03%. MINIMIZE
EXPO SURE BY APPLYING PROPER HANDLING TECHNIQUES & USE OF PERSONAL
PROTECTIVE GEAR.

HCC:F3
Boiling Pt:=132.2C, 270.F
Vapor Pres:5.1 MM HG
Spec Gravity:0.99
pH:NA
Evaporation Rate & Reference:9.5 (ETHYL ETHER)
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK RED LIQUID, AROMATIC ODOR.
Percent Volatiles by Volume:65

Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, MAY REACT WITH REDUCING AGENTS TO LIBERATE FREE
AMINE(S).
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS OF USE.
AVOID HIGH TEMPERATURES.
Hazardous Decomposition Products:SMOKE, SOOT, AND TOXIC/IRRITATING
FUMES (I.E., CARBON DIOXIDE, CARBON MONOXIDE, ETC.). OXIDES OF
NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:WHEN A DECISION IS MADE TO DISCARD THIS MATERIAL
AS SUPPLIED, IT MEETS RCRA'S CHARACTERISTIC DEFINITION OF
IGNITABILITY. FEDERAL REGULATIONS MAY APPLY TO EMPTY CONTAINER.
STATE AND/OR LOCAL REGULATION S MAY BE DIFFERENT. OF THE METHODS OF
DISPOSAL CURRENTLY AVAILABE, IT IS RECOMMENDED THAT AN ALTERNA TIVE
BE SELECTED.

Toxicological Information:C.I. SOLVENT RED 164: THE DYE EXHIBITED
MUTAGENIC ACTIVITY DURING A STUDY ON CYTOTOXICITY.
NO-TOXIC-EFFECT-LEVEL: 40 MG/KG/DAY. A STUDY INDICATED THAT
SENSITIZATION WAS NOT INDUCED. XYLENE: THIS CHEMI CAL CAUSED FETAL
INJURY DURING A STUDY ON LAB ANIMALS. ADVERSE EFFECTS NOTED,
W/ETHYL ALCOHOL, TO LIVER & KIDNEY. ORAL LD50 (RAT): 3523 MG/KG;
DERMAL LD50 (RABBIT): >5 ML/KG. INHALATION LC50 (RAT): 50 00 PPM/4
HRS. ETHYL BENZENE: DURING A 2 YEAR STUDY THERE WAS CLEAR EVIDENCE
OF CARCINOGENIC ACTIVITY. EXPOSURE TO LAB ANIMALS HAS CAUSED SOME
FETOTOXIC EFFECTS AT DOSES THAT WOULD CAUSES MATERNAL TOXI CITY.
ORAL LD50 (RAT): 3500 MG/KG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA AVAILABLE ON THIS PRODUCT.

Transport Information:SHIPPING NAME: XYLENES SOLUTION DOT, IATA, IMO).
DOT LABEL:FLAMMABLE LIQUID. UN/NA NUMBER: UN 1307. DOT LABEL NO.:
WD3. HAZARD CLASS: 3 (IATA/49 CFR), 3.3 (IMO). PACKING GROUP III.
RQ: >357 LBS.

SARA Title III Information:SARA TITLE III SECTION 311/312: HAZARD
CATAGORIES: FIRE-YES; SUDDEN RELEASE-NO; REACTIVITY-NO; IMMEDIATE
(ACUTE)-YES; DELAYED (CHRONIC)-YES. SARA SECTION 302 EXTREMELY
HAZARDOUS MATERIAL: NO REGULATED INGREDIENTS. SARA SECTION 313
TOXIC CHEMICALS: XYLENE, ETHYL BENZENE.
Federal Regulatory Information:TSCA SECTION 8(B) DATA REPORTING RULE.
OZONE DEPLETING CHEMICALS: NO REGULATED INGREDIENTS.
State Regulatory Information:PENNSYLVANIA & NEW JERSEY R-T-K: C.I.
SOLVENT RED 164, 65%; XYLENE, CAS# 1330-20-7, 28%, ENVIRONMENTAL
HAZARD; ETHYL BENZENE, CAS# 100-41-4, 7%, ENVIRONMENTAL HAZARD;
NON-HAZARDOUS TRADE SECRET INGRED IENT(S), CAS# PROPRIETARY,
%=BALANCE. CALIFORNIA PROPOSITION 65: NO REGULATED INGREDEINMTS.